Silver(I) and thallium(I) cations as unsupported bridges between two metal bases.

نویسندگان

  • Holger Braunschweig
  • Rian D Dewhurst
  • Florian Hupp
  • Christoph Schneider
چکیده

Stirring Lewis-basic transition metal complexes with the salts M[BAr(Cl)4] (M = Ag, Tl; Ar(Cl) = 3,5-C6H3Cl2) resulted in the formation of diplatinum complexes [{(Cy3P)2Pt}2(μ-Ag)][BAr(Cl)4] (3) and [{(Cy3P)2Pt}2(μ-Tl)][BAr(Cl)4] (4) and the diiron compound [{(OC)3(Me3P)2Fe}2(μ-Ag)] (5) featuring bridging, unsupported metal cations. Their properties were investigated by multinuclear NMR spectroscopy, as well as X-ray diffraction and infrared measurements.

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عنوان ژورنال:
  • Chemical communications

دوره 50 99  شماره 

صفحات  -

تاریخ انتشار 2014